The finding of the soft-hard nature of the nanoparticle assemblies and their interactions with contacting substrates could form the basis of a new strategy for manipulating nanoscale linkages between nanoparticle assemblies, soldering nanoelectronics, and constructing nanosensor devices. The morphological properties of the spherical assemblies have been characterized using TEM, AFM, and SAXS techniques. The combination of the mediation force of the multidentate thioether and the hydrophobic force of the tetraalkylammonium template establishes the interparticle linkage and stability. This strategy explores multidentate thioether ligands as molecular mediators and tetraalkylammonium-capped gold nanoparticles (5 nm) as templates toward the preparation of size-controllable and monodispersed spherical assemblies ( approximately 20-300-nm diameters). This paper reports findings of an investigation of a mediator-template strategy for the size-controllable assembly of nanoparticles. The ability to construct size- and shape-controllable architectures using nanoparticles as building blocks is essential for the exploration of nanoparticle-structured properties.
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